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10000629
Mathematical Modeling for Continuous Reactive Extrusion of Poly Lactic Acid formation by Ring Opening Polymerization Considering Metal/Organic Catalyst and Alternative Energies
Abstract:
PLA emerged as a promising polymer because of its property as a compostable, biodegradable thermoplastic made from renewable sources. PLA can be polymerized from monomers (Lactide or Lactic acid) obtained by fermentation processes from renewable sources such as corn starch or sugarcane. For PLA synthesis, ring opening polymerization (ROP) of Lactide monomer is one of the preferred methods. In the literature, the technique mainly developed for ROP of PLA is based on metal/bimetallic catalyst (Sn, Zn and Al) or other organic catalysts in suitable solvent. However, the PLA synthesized using such catalysts may contain trace elements of the catalyst which may cause toxicity. This work estimated the usefulness and drawbacks of using different catalysts as well as effect of alternative energies and future aspects for PLA production.
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References:

[1] S. Jacobsen, H.-G. Fritz, P.Degée, P.Dubois, and R.Jérôme, “Continuous reactive extrusion polymerisation of L-lactide ― an engineering view,” Macromol. Symp., vol. 153, no. 1, pp. 261–273, 2000.
[2] K. Madhavan Nampoothiri, N. R. Nair, and R. P. John, “An overview of the recent developments in polylactide (PLA) research,” Bioresour. Technol., vol. 101, no. 22, pp. 8493–8501, Nov. 2010.
[3] P. Dubois, C. Jacobs, R. Jerome, and P. Teyssie, “Macromolecular engineering of polylactones and polylactides. 4. Mechanism and kinetics of lactide homopolymerization by aluminum isopropoxide,” Macromolecules, vol. 24, no. 9, pp. 2266–2270, Apr. 1991.
[4] D. R. Witzke, R. Narayan, and J. J. Kolstad, “Reversible Kinetics and Thermodynamics of the Homopolymerization of l-Lactide with 2- Ethylhexanoic Acid Tin(II) Salt,” Macromolecules, vol. 30, no. 23, pp. 7075–7085, Nov. 1997.
[5] N. E. Kamber, W. Jeong, R. M. Waymouth, R. C. Pratt, B. G. G. Lohmeijer, and J. L. Hedrick, “Organocatalytic ring-opening polymerization,” Chem. Rev., vol. 107, no. 12, pp. 5813–5840, 2007.
[6] W. Jeong, J. L. Hedrick, and R. M. Waymouth, “Organic Spirocyclic Initiators for the Ring-Expansion Polymerization of β-Lactones,” J. Am. Chem. Soc., vol. 129, no. 27, pp. 8414–8415, Jul. 2007.
[7] M. Myers, E. F. Connor, T. Glauser, A. Möck, G. Nyce, and J. L. Hedrick, “Phosphines: Nucleophilic organic catalysts for the controlled ring-opening polymerization of lactides,” J. Polym. Sci. Part Polym. Chem., vol. 40, no. 7, pp. 844–851, Apr. 2002.
[8] I. Başaran and A. Oral, “Synthesis and Characterization of Poly(L-Lactic acid)/Clay Nanocomposite via Metal-Free Process,” Polym.-Plast. Technol. Eng., vol. 52, no. 12, pp. 1271–1276, 2013.
[9] “InnoREX.” (Online). Available: http://www.innorex.eu/about.php.
[10] S. Jing, W. Peng, Z. Tong, and Z. Baoxiu, “Microwave-irradiated ringopening polymerization of D,L-lactide under atmosphere,” J. Appl. Polym. Sci., vol. 100, no. 3, pp. 2244–2247, May 2006.
[11] P. Albert, H. Warth, R. Mülhaupt, and R. Janda, “Comparison of thermal and microwave-activated polymerization of ε-caprolactone with titanium tetrabutylate as catalyst,” Macromol. Chem. Phys., vol. 197, no. 5, pp. 1633–1641, May 1996.
[12] A. Södergård and M. Stolt, “Industrial Production of High Molecular Weight Poly(Lactic Acid),” in Poly(Lactic Acid), R. Auras, L.-T. Lim, S. E. M. Selke, and H. Tsuji, Eds. John Wiley & Sons, Inc., 2010, pp. 27–41.
[13] R. Mehta, V. Kumar, and S. N. Upadhyay, “Mathematical Modeling of the Poly(lactic acid) Ring–Opening Polymerization Kinetics,” Polym.- Plast. Technol. Eng., vol. 46, no. 3, pp. 257–264, 2007.
[14] I. Banu, J.-P. Puaux, G. Bozga, and I. Nagy, “Modeling of L-lactide Polymerization by Reactive Extrusion,” Macromol. Symp., vol. 289, no. 1, pp. 108–118, 2010.
[15] Y. Yu, G. Storti, and M. Morbidelli, “Ring-Opening Polymerization of l,l-Lactide: Kinetic and Modeling Study,” Macromolecules, vol. 42, no. 21, pp. 8187–8197, Nov. 2009.
[16] “Compounding and extrusion - Fraunhofer ICT.” (Online). Available: http://www.ict.fraunhofer.de/en/comp/pe/ce.html.
[17] Y. Yu, G. Storti, and M. Morbidelli, “Kinetics of Ring-Opening Polymerization of l,l-Lactide,” Ind. Eng. Chem. Res., vol. 50, no. 13, pp. 7927–7940, Jul. 2011.
[18] L. J. Liu, C. Zhang, L. Q. Liao, X. L. Wang, and R. X. Zhuo, “Microwave-assisted Polymerization of D, L-Lactide with Stannous Octanoate as Catalyst,” Chin. Chem. Lett., vol. 12, no. 8, pp. 663–664, 2001.
[19] M. Vukomanović, M. Mitrić, S. D. Škapin, E. Žagar, J. Plavec, N. Ignjatović, and D. Uskoković, “Influence of ultrasonic processing on the macromolecular properties of poly (d,l-lactide-co-glycolide) alone and in its biocomposite with hydroxyapatite,” Ultrason. Sonochem., vol. 17, no. 5, pp. 902–908, Jun. 2010.
[20] C. Zhang, L. Liao, and L. Liu, “Rapid Ring-Opening Polymerization of D,L-Lactide by Microwaves,” Macromol. Rapid Commun., vol. 25, no. 15, pp. 1402–1405, Aug. 2004.
[21] “Ludovic - Twin screw extrusion - SCConsultants.” (Online). Available: http://www.scconsultants.com/en/ludovic-twin-screw-simulationsoftware. html..
[22] “Purac home.” (Online). Available: http://www.purac.com/.
[23] “NatureWorks LLC Home Page.” (Online). Available: http://www.natureworksllc.com/.
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